Abstract
We investigated the chemical, physical, and tribological properties of nanolubricants consisting of epoxidized sunflower oil with Cu nanoparticles as additive. These latter are produced by magnetron sputtering at distinct current levels in the deposition, to improve the development of nanolubricants by enhancing the nanoparticles dispersion. The nanolubricants are here characterized by Fourier transform infrared spectroscopy, zeta potential, ultraviolet–visible absorbance spectroscopy, small-angle X-ray scattering, and scanning electron microscopy. After all, the tribological properties of the bionanolubricants are investigated using a high-frequency reciprocating rig equipment, scanning electron microscopy, and energy dispersive spectroscopy. Our results disclose the nanolubricants produced using the magnetron sputtering technique have excellent nanoparticle dispersion, as well as good tribological performance.
Issue Section:
Micro-Nano Tribology
References
1.
Gulzar
, M.
, Masjuki
, H. H.
, Kalam
, M. A.
, Varman
, M.
, Zulkifli
, N. W. M.
, Mufti
, R. A.
, and Zahid
, R.
, 2016
, “Tribological Performance of Nanoparticles as Lubricating oil Additives
,” J. Nanopart. Res.
, 18
(8
), p. 223
. 10.1007/s11051-016-3537-42.
Spikes
, H.
, 2015
, “Friction Modifier Additives
,” Tribol. Lett.
, 60
(1
), p. 5
. 10.1007/s11249-015-0589-z3.
Li
, W.
, Zheng
, S.
, Ma
, S.
, Ding
, H.
, Jiao
, D.
, and Cao
, B.
, 2010
, “Study of Surface Modification of ZrO2/SiO2 Nanocomposites With Aluminum Zirconium Coupling Agent
,” Asian—J. Chem.
, 23
, p. 705
.4.
Zhang
, B.-S.
, Xu
, B.-S.
, Xu
, Y.
, Gao
, F.
, Shi
, P.-J.
, and Wu
, Y.-X.
, 2011
, “Cu Nanoparticles Effect on the Tribological Properties of Hydrosilicate Powders as Lubricant Additive for Steel–Steel Contacts
,” Tribol. Int.
, 44
(7–8
), p. 878
. 10.1016/j.triboint.2011.03.0025.
Yu
, H. L.
, Xu
, Y.
, Shi
, P. J.
, Xu
, B. S.
, Wang
, X. L.
, Liu
, Q.
, and Wang
, H. M.
, 2008
, “Characterization and Nano-Mechanical Properties of Tribofilms Using Cu Nanoparticles as Additives
,” Surf. Coat. Technol.
, 203
(1–2
), p. 28
. 10.1016/j.surfcoat.2008.07.0326.
Hernandez Battez
, A.
, Fernandez Rico
, J. E.
, Navas Arias
, A.
, Viesca Rodriguez
, J. L.
, Chou Rodriguez
, R.
, and Diaz Fernandez
, J. M.
, 2006
, “The Tribological Behaviour of ZnO Nanoparticles as an Additive to PAO6
,” Wear
, 261
(3–4
), p. 256
. 10.1016/j.wear.2005.10.0017.
Wu
, Y.
, and Kao
, M.
, 2011
, “Using TiO2 Nanofluid Additive for Engine Lubrication oil
,” Ind. Lubr. Tribol.
, 63
(6
), p. 440
. 10.1108/003687911111690258.
Xie
, H.
, Jiang
, B.
, He
, J.
, Xia
, X.
, and Pan
, F.
, 2016
, “Lubrication Performance of MoS2 and SiO2 Nanoparticles as Lubricant Additives in Magnesium Alloy-Steel Contacts
,” Tribol. Int.
, 93
(Part A
), p. 63
. 10.1016/j.triboint.2015.08.0099.
Padgurskas
, J.
, Rukuiza
, R.
, Prosycevas
, I.
, and Kreivaitis
, R.
, 2013
, “Tribological Properties of Lubricant Additives of Fe, Cu and Co Nanoparticles
,” Tribol. Int.
, 60
, p. 224
. 10.1016/j.triboint.2012.10.02410.
Li
, Y.
, Liu
, T.
, Zhang
, Y.
, Zhang
, P.
, and Zhang
, S.
, 2018
, “Study on the Tribological Behaviors of Copper Nanoparticles in Three Kinds of Commercially Available Lubricants
,” Ind. Lubr. Tribol.
, 70
(3
), p. 519
. 10.1108/ILT-05-2017-014311.
Singh
, N.
, Singh
, Y.
, Sharma
, A.
, and Singla
, A.
, 2019
, “Effect of Addition of Copper Nanoparticles on the Tribological Behavior of Macadamia oil at Different Sliding Speeds
,” Energy Sources, Part A: Recovery, Utilization, and Environ-mental Effects
, 41
(23
), p. 2917
. 10.1080/15567036.2019.158273412.
Alves
, S. M.
, Mello
, V. S.
, Faria
, E. A.
, and Camargo
, A. P. P.
, 2016
, “Nanolubricants Developed From Tiny CuO Nanoparticles
,” Tribol. Int.
, 100
, p. 263
. 10.1016/j.triboint.2016.01.05013.
Yang
, G.-b.
, Chai
, S.-t.
, Xiong
, X.-j.
, Zhang
, S.-m.
, Yu
, L.-g.
, and Zhang
, P.-y.
, 2012
, “Preparation and Tribological Properties of Surface Modified Cu Nanoparticles
,” Transactions Nonferrous Metals Soc. China
, 22
(2
), p. 366
. 10.1016/S1003-6326(11)61185-014.
Choi
, Y.
, Lee
, C.
, Hwang
, Y.
, Park
, M.
, Lee
, J.
, Choi
, C.
, and Jung
, M.
, 2009
, “Tribological Behavior of Copper Nanoparticles as Additives in oil
,” Current Appl. Phys.
, 9
(2
), p. e124
. 10.1016/j.cap.2008.12.05015.
Zhou
, J.
, Yang
, J.
, Zhang
, Z.
, Liu
, W.
, and Xue
, Q.
, 1999
, “Study on the Structure and Tribological Properties of Surface-Modified cu Nanoparticles
,” Mater. Res. Bull.
, 34
(9
), p. 1361
. 10.1016/S0025-5408(99)00150-616.
Kumar
, A.
, Thakre
, G. D.
, Arya
, P. K.
, and Jain
, A. K.
, 2017
, “Influence of Operating Parameters on the Tribological Performance of Oleic Acid-Functionalized Cu Nanofluids
,” Ind. Eng. Chem. Res.
, 56
(13
), p. 3527
. 10.1021/acs.iecr.6b0437517.
Torimoto
, T.
, Okazaki
, K.-i.
, Kiyama
, T.
, Hirahara
, K.
, Tanaka
, N.
, and Kuwabata
, S.
, 2006
, “Sputter Deposition Onto Ionic Liquids: Simple and Clean Synthesis of Highly Dispersed Ultrafine Metal Nanoparticles
,” Appl. Phys. Lett.
, 89
(24
), p. 243117
. 10.1063/1.240497518.
Wender
, H.
, de Oliveira
, L. F.
, Feil
, A. F.
, Lissner
, E.
, Migowski
, P.
, Meneghetti
, M. R.
, Teixeira
, S. R.
, and Dupont
, J.
, 2010
, “Synthesis of Gold Nanoparticles in a Biocompatible Fluid From Sputtering Deposition Onto Castor oil
,” Chem. Commun.
, 46
(37
), p. 7019
. 10.1039/c0cc01353f19.
Hwang
, Y.
, Lee
, J.-K. J.-K.
, Lee
, J.-K. J.-K.
, Jeong
, Y.-M.
, Cheong
, S.-i.
, Ahn
, Y.-C.
, and Kim
, S. H.
, 2008
, “Production and Dispersion Stability of Nanoparticles in Nanofluids
,” Powder Technol.
, 186
(2
), p. 145
. 10.1016/j.powtec.2007.11.02020.
Flores-Castañeda
, M.
, Campos
, E.
, Camacho-López
, M.
, Muhl
, S.
, García
, E.
, and Figueroa
, M.
, 2015
, “Bismuth Nanoparticles Synthesized by Laser Ablation in Lubricant Oils for Tribological Tests
,” J. Alloys Compd.
, 643
(1
), p. S67
. 10.1016/j.jallcom.2014.12.05421.
Sadrolhosseini
, A. R.
, Abdul Rashid
, S.
, Zakaria
, A.
, and Shameli
, K.
, 2016
, “Green Fabrication of Copper Nanoparti-Cles Dispersed in Walnut Oil Using Laser Ablation Technique
,” J. Nanomater.
, 2016
, p. 1
. 10.1155/2016/806968522.
Zamiri
, R.
, Zakaria
, A.
, Ahangar
, H. A.
, Sadrolhosseini
, A. R.
, and Mahdi
, M. A.
, 2010
, “Fabrication of Silver Nanoparticles Dispersed in Palm Oil Using Laser Ablation
,” Int. J. Mol. Sci.
, 11
(11
), p. 4764
. 10.3390/ijms1111476423.
Hatami
, M.
, Hasanpour
, M.
, and Jing
, D.
, 2020
, “Recent Developments of Nanoparticles Additives to the Consumables Liquids in Internal Combustion Engines: Part II: Nano-Lubricants
,” J. Mol. Liq.
, 319
, p. 114156
. 10.1016/j.molliq.2020.11415624.
Aberoumand
, S.
, and Jafarimoghaddam
, A.
, 2017
, “Experimental Study on Synthesis, Stability, Thermal Conductivity and Viscosity of Cu–Engine Oil Nanofluid
,” J. Taiwan Inst. Chem. Eng.
, 71
, p. 315
. 10.1016/j.jtice.2016.12.03525.
Alves
, S. M.
, Barros
, B. S.
, Trajano
, M. F.
, Ribeiro
, K. S. B.
, and Moura
, E.
, 2013
, “Tribological Behavior of Vegetable Oil-Based Lubricants with Nanoparticles of Oxides in Boundary Lubrication Conditions
,” Tribol. Int.
, 65
, p. 28
. 10.1016/j.triboint.2013.03.02726.
Maru
, M. M.
, and Tanaka
, D. K.
, 2007
, “Consideration of Stribeck Diagram Parameters in the Investigation on Wear and Friction Behavior in Lubricated Sliding
,” J. Brazilian Soc. Mech. Sci. Eng.
, 29
(1
), p. 55
. 10.1590/s1678-5878200700010000927.
Salimon
, J.
, Salih
, N.
, and Yousif
, E.
, 2011
, “Chemically Modified Biolubricant Basestocks From Epoxidized Oleic Acid: Improved low Temperature Properties and Oxidative Stability
,” J. Saudi Chem. Soc.
, 15
(3
), p. 195
. 10.1016/j.jscs.2010.08.00428.
Calvo
, P.
, Vila-Jato
, J. L.
, and Alonso
, M. J.
, 1996
, “Comparative in Vitro Evaluation of Several Colloidal Systems, Nanoparticles, Nanocapsules, and Nanoemulsions, as Ocular Drug Carriers
,” J. Pharm. Sci.
, 85
(5
), p. 530
. 10.1021/js950474+29.
Magenhein
, B.
, and Benita
, S.
, 1991
, “Nanoparticle Characterization: a Comprehensive Physicochemical Approach
,” S.T.P. Pharma Sciences
, 1
, p. 221
.30.
Mosqueira
, V. C. F.
, Legrand
, P.
, Pinto-Alphandary
, H.
, Puisieux
, F.
, and Barratt
, G.
, 2000
, “Poly(D,L-Lactide) Nanocapsules Prepared by a Solvent Displacement Process: Influence of the Composition on Physicochemical and Structural Properties
,” J. Pharm. Sci.
, 89
(5
), p. 614
. 10.1002/(sici)1520-6017(200005)31.
de Oliveira
, J. F. A.
, and Cardoso
, M. B.
, 2014
, “Partial Aggregation of Silver Nanoparticles Induced by Capping and Reducing Agents Competition
,” Langmuir
, 30
(17
), p. 4879
. 10.1021/la403635c32.
Singh
, M.
, Sinha
, I.
, Premkumar
, M.
, Singh
, A. K.
, and Mandal
, R. K.
, 2010
, “Structural and Surface Plasmon Behavior of Cu Nanoparticles Using Different Stabilizers
,” Colloids Surf., A
, 359
(1–3
), p. 88
. 10.1016/j.colsurfa.2010.01.06933.
Joseph
, Y.
, Besnard
, I.
, Rosenberger
, M.
, Guse
, B.
, Nothofer
, H.-G.
, Wessels
, J. M.
, Wild
, U.
, Knop-Gericke
, A.
, Su
, D.
, Schlogl
, R.
, Yasuda
, A.
, and Vossmeyer
, T.
, 2003
, “Self-Assembled Gold Nanoparticle/Alkanedithiol Films: Preparation, Electron Microscopy, XPS-Analysis, Charge Transport, and Vapor-Sensing Properties †
,” J. Phys. Chem. B
, 107
(30
), p. 7406
. 10.1021/jp030439o34.
Khadempir
, F.
, Askari
, H. R.
, and Nejad
, A. A.
, 2019
, “Investigation of Nonlinear Absorption and the Electromagnetically Induced Transparency in a SMNP-SQD Hybrid System by Using the Mie Theory
,” Optik
, 178
, p. 51
. 10.1016/j.ijleo.2018.09.15535.
Santos
, J.
, Santos
, M.
, Thesing
, A.
, Tavares
, F.
, Griep
, J.
, and Rodrigues
, M.
, 2016
, “Ressonância de Plasmon de Superfície Localizado e Aplicação em Biossensores e Células Solares
,” Química Nova
, 39
(9
), p. 1098
. 10.21577/0100-4042.2016012636.
37.
Schnablegger
, H.
, and Singh
, Y.
, 2013
, The SAXS Guide—Getting Acquainted with the Principles
, AntonPaar GmbH
, Austria
.38.
Petoukhov
, M. V.
, Franke
, D.
, Shkumatov
, A. V.
, Tria
, G.
, Kikhney
, A. G.
, Gajda
, M.
, Gorba
, C.
, Mertens
, H. D. T.
, Konarev
, P. V.
, and Svergun
, D. I.
, 2012
, “New Developments in the ATSAS Program Package for Small-Angle Scattering Data Analysis
,” J. Appl. Crystallogr.
, 45
(2
), p. 342
. 10.1107/S002188981200766239.
Franke
, D.
, Petoukhov
, M. V.
, Konarev
, P. V.
, Panjkovich
, A.
, Tuukkanen
, A.
, Mertens
, H. D. T.
, Kikhney
, A. G.
, Hajizadeh
, N. R.
, Franklin
, J. M.
, Jeffries
, C. M.
, and Svergun
, D. I.
, 2017
, “ATSAS 2.8: a Comprehensive Data Analysis Suite for Small-Angle Scattering From Macromolecular Solutions
,” J. Appl. Crystallogr.
, 50
(4
), p. 1212
. 10.1107/S160057671700778640.
Wender
, H.
, Migowski
, P.
, Feil
, A. F.
, Teixeira
, S. R.
, and Dupont
, J.
, 2013
, “Sputtering Deposition of Nanoparticles Onto Liquid Substrates: Recent Advances and Future Trends
,” Coord. Chem. Rev.
, 257
(17–18
), p. 2468
. 10.1016/j.ccr.2013.01.01341.
Kumar
, G.
, Garg
, H. C.
, and Gijawara
, A.
, 2019
, “Experimental Investigation of Tribological Effect on Vegetable Oil With CuO Nanoparticles and ZDDP Additives
,” Ind. Lubr. Tribol.
, 71
(3
), p. 499
. 10.1108/ILT-05-2018-019642.
Alves
, S. M.
, Silva e Mello
, V.
, and Sinatora
, A.
, 2018
, “Nanolubrication Mechanisms: Influence of Size and Concentration of CuO Nanoparticles
,” Mater. Performance Charact.
, 7
(3
), p. 20170064
. 10.1520/MPC2017006443.
Guo
, Z.
, Zhang
, Y.
, Wang
, J.
, Gao
, C.
, Zhang
, S.
, Zhang
, P.
, and Zhang
, Z.
, 2020
, “Interactions of Cu Nanoparticles with Conventional Lubricant Additives on Tribological Performance and Some Physicochemical Properties of an Ester Base oil
,” Tribol. Int.
, 141
, p. 105941
. 10.1016/j.triboint.2019.10594144.
Hu
, C.
, Bai
, M.
, Lv
, J.
, Liu
, H.
, and Li
, X.
, 2014
, “Molecular Dynamics Investigation of the Effect of Copper Nanoparticle on the Solid Contact Between Friction Surfaces
,” Appl. Surf. Sci.
, 321
, p. 302
. 10.1016/j.apsusc.2014.10.006Copyright © 2021 by ASME
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