Important from exploitation point of view mechanical properties of single-layer, double-layer, and mixed alumina and ceria films and their stainless steel (SS) substrate were investigated by means of nanoindentation experiments. As a result, we obtained the experimental load–displacement curves and calculated the indentation hardness (HIT) and indentation modulus (EIT), by means of Oliver and Pharr approximation method. Numerical simulations of the process of nanoindentation by means of finite element method were performed as well, in order to obtain more information about the plastic properties of the investigated films. The obtained results show that the mixed Al2O3+Ce2O3 film, obtained at dominant concentration of cerium ions in the working electrolyte, has the highest indentation hardness and modulus, followed by the single Ce2O3-CeO2 film, the mixed Al2O3+Ce2O3 film, obtained at dominant concentration of aluminum ions in the working electrolyte, the double Ce2O3-CeO2/Al2O3 layer, and single Al2O3 layer.

References

1.
Mansfeld
,
M.
,
Wang
,
Y.
, and
Shin
,
H.
,
1992
, “
The Ce-Mo Process for the Development of a Stainless Aluminum
,”
Electrochim. Acta
,
37
(
12
), pp.
2277
2282
.
2.
Bernal
,
S.
,
Botana
,
F. J.
,
Calvino
,
J. J.
,
Marcos
,
M.
,
Pérez-Omil
,
J. A.
, and
Vidal
,
H.
,
1995
, “
Lanthanide Salts as Alternative Corrosion Inhibitors
,”
J. Alloys Compd.
,
225
(
1–2
), pp.
638
641
.
3.
Hussey
,
R. J.
, and
Graham
,
M. J.
,
1996
, “
The Influence of Reactive-Element Coatings on the High-Temperature Oxidation of Pure-Cr and High-Cr-Content Alloys
,”
Oxid. Met.
,
45
(
3–4
), pp.
349
374
.
4.
Mansfeld
,
F.
,
Breslin
,
C. B.
,
Pardo
,
A.
, and
Perez
,
F. J.
,
1997
, “
Surface Modification of Stainless-Steels-Green Technology for Corrosion Protection
,”
Surf. Coat. Technol.
,
90
(
3
), pp.
224
228
.
5.
Montemor
,
M. F.
,
Simones
,
A. M.
, and
Ferreira
,
M. G. S.
,
2002
, “
Composition and Corrosion Behavior of Galvanized Steel Treated With Rare-Earth Salts: The Effect of the Cation
,”
Prog. Org. Coat
,
44
(
2
), pp.
111
120
.
6.
Abreu
,
C. M.
,
Cristobal
,
M. J.
,
Novoa
,
X. R.
,
Pena
,
G.
,
Perez
,
M. C.
, and
Rodriguez
,
R. J.
,
2002
, “
Modifications of the Stainless Steels Passive Film Induced by Cerium Implantation
,”
Surf. Coat. Technol.
,
158–159
, pp.
582
587
.
7.
Fauvet
,
P.
,
Balbaud
,
F.
,
Robin
,
R.
,
Tran
,
Q.-T.
,
Mugnier
,
A.
, and
Espinoux
,
D.
,
2008
, “
Corroson Mechanisms of Austenitic Stainless Steels in Nitric Media Used in Reprocessing Plants
,”
J. Nucl. Mater.
,
375
(
1
), pp.
52
64
.
8.
Kain
,
V.
,
Khan
,
S.
,
Reddy
,
A. V. R.
, and
Wattal
,
P. K.
,
2013
, “
Corrosion of Non-Sensitized Austenitic Stainless Steels in Nitric Acid Environment: An Electrochemical Approach
,”
Adv. Mater. Res.
,
794
, pp.
517
529
.
9.
Stoyanova
,
E.
,
Nikolova
,
D.
,
Stoychev
,
D.
,
Stefanov
,
P.
, and
Marinova
,
T.
,
2006
, “
Effect of Al and Ce Oxide Layers Electrodeposited on OC4004 Stainless Steel on Its Corrosion Characteristics in Acid Media
,”
Corr. Sci.
,
48
(
12
), pp.
4037
4052
.
10.
Guergova
,
D.
,
Stoyanova
,
E.
,
Stoychev
,
D.
,
Atanasova
,
G.
,
Avramova
,
I.
, and
Stefanov
,
P.
,
2008
, “
Influence of Calcination of Stainless Steel OC404 Covered With Alumina or Ceria Carrier Layers on Their Passive State in Different Acid Media
,”
Bulg. Chem. Commun.
,
40
(
3
), pp.
227
232
.
11.
Stoyanova
,
E.
,
Guergova
,
D.
,
Stoychev
,
D.
,
Avramova
,
I.
, and
Stefanov
,
P.
,
2010
, “
Passivity of OC404 Steel Modified Electrochemically With CeO2-Ce2O3 Layers in Sulfuric Acid Media
,”
Electrochim. Acta
,
55
(
5
), pp.
1725
1732
.
12.
Guergova
,
D.
,
Stoyanova
,
E.
,
Stoychev
,
D.
,
Avramova
,
I.
,
Atanasova
,
G.
, and
Stefanov
,
P.
,
2011
, “
Corrosion Stability of Stainless Steel, Modified Electrochemically With Ce2O3-CeO2 Films, in 3.5% NaCl Media
,”
Bulg. Chem. Commun.
,
43
(
1
), pp.
150
157
http://www.bcc.bas.bg/BCC_Volumes/Volume_43_Number_1_2011/Volume_43_Number_1_2011_PDF/2011-43-1_24.pdf.
13.
Guergova
,
D.
,
Stoyanova
,
E.
,
Stoychev
,
D.
,
Avramova
,
I.
, and
Stefanov
,
P.
,
2012
, “
Investigation of the Inhibiting Effect of Cerium Ions on the Corrosion Behavior of OC404 Stainless Steel in Sulfuric Acid Medium
,”
Open Chem. Phys. J
,
4
(
1
), pp.
8
17
.
14.
Guergova
,
D.
,
Stoyanova
,
E.
,
Stoychev
,
D.
,
Avramova
,
I.
, and
Stefanov
,
P.
,
2015
, “
Self-Healing Effect of Ceria Electrodeposited Thin Films on Stainless Steel in Aggressive 0.5 Mol/L NaCl Aqueous Solution
,”
J. Rare Earths
,
33
(
11
), pp.
1212
1227
.
15.
Stoychev
,
D.
,
2013
, “
Corrosion Protective Ability of Electrodeposited Ceria Layers
,”
J. Solid State Electrochem.
,
17
(
2
), pp.
497
509
.
16.
Avramova
,
I.
,
Stefanov
,
P.
,
Nicolova
,
D.
,
Stoychev
,
D.
, and
Marinova
,
T.
,
2005
, “
Characterization of Nanocomposite CeO2-Al2O3 Coatings Electrodeposited on Stainless Steel
,”
Comp. Sci. Technol.
,
65
(
11–12
), pp.
1663
1667
.
17.
Avramova
,
I.
,
Suzer
,
S.
,
Guergova
,
D.
,
Stoychev
,
D.
, and
Stefanov
,
P.
,
2013
, “
CeOx/Al2O3 Thin Films on Stainless Steel Substrate—Dynamical X-Ray Photoelectron Spectroscopy Investigations
,”
Thin Solid Films
,
536
, pp.
63
67
.
18.
Guergova
,
D.
,
Stoyanova
,
E.
,
Avramova
,
I.
, and
Stoychev
,
D.
,
2018
, “
Electrochemical Deposition of Mixed Ce-Al Oxide Layers on Stainless Steel and Assessment of Their Corrosion-Protective Ability
,”
Rev. De Chimie
(in press).
19.
Guergova
,
D.
,
Stoyanova
,
E.
,
Avramova
,
I.
, and
Stoychev
,
D.
,
2017
, “
Electrochemical Deposition of Mixed Ce-Al Oxide Layers on Stainless Steel and Assessment of Their Corrosion-Protective Ability
,” “
XII ECHEMS Meeting “Electrochemistry in Ingenious Molecules, Surfaces and Devices, Programme
”-Book of Abstracts, Publisher XII ECHEMS, Milano Marittima, Italy, SURF P5, p.
116
.
20.
Nonneman
,
M.
,
1990
, “
New High-Performance Gas Flow Equalizing Metal Supports For Automotive Exhaust Gas Catalysts
,”
SAE Int. J. Fuels Lubr.
,
99
(4), pp.
108
116
https://www.jstor.org/stable/44580374?seq=1#page_scan_tab_contents.
21.
Lox
,
E. S. J.
, and
Engler
,
B. H.
,
1997
, “
Environmental Catalysis-Mobile Sources
,”
Handbook of Heterogeneous Catalysis
,
G.
Ertl
,
H.
Knözinger
, and
J.
Weitkamp
, eds., Vol.
4
,
Wiley-VCH
, Weinheim, Germany, pp.
1559
1633
.
22.
Yazawa
,
Y.
,
Yoshida
,
H.
,
Takagi
,
N.
,
Komai
,
S.
,
Satsuma
,
A.
, and
Hattori
,
T.
,
1999
, “
Acid Strenght of Support Materials as a Factor Controlling Oxidation State of Palladium Catalyst for Propane Combustion
,”
J. Catal.
,
187
(
1
), pp.
15
23
.
23.
Oliver
,
W. C.
, and
Pharr
,
G. M.
,
1992
, “
An Improved Technique for Determining Hardness and Elastic Modulus Using Load and Displacement Sensing Indentation Experiments
,”
J. Mater. Res
,
7
(
6
), pp.
1564
1583
.
24.
Iankov
,
R.
,
Cherneva
,
S.
, and
Stoychev
,
D.
,
2008
, “
Investigation of Material Properties of Thin Copper Films Through Finite Element Modeling of Microindentation Test
,”
Appl. Surf. Sci.
,
254
(
17
), pp.
5460
5469
.
25.
Zamfirova
,
G.
,
Cherneva
,
S.
,
Gaydarov
,
V.
, and
Djourelov
,
N.
,
2014
, “
Nanocomposites Based on Epoxy Resin. Simulation of Microindentation Process
,”
Colloids Surf. A
,
460
, pp.
254
264
.
26.
Kanchana
,
V.
,
Vaitheeswaran
,
G.
,
Svane
,
A.
, and
Delin
,
A.
,
2006
, “
First-Principles Study of Elastic Properties of CeO2, ThO2 and PoO2
,”
J. Phys.: Condens. Matter
,
18
(
42
), pp.
9615
9624
.
27.
Chen
,
Y. J.
,
Sun
,
Y.
,
Liu
,
Y. Z.
, and
Cui
,
Z. W.
,
2011
, “
Molecular Dynamics (MD Simulation of Uniaxial Tension of Ceria and Gadolinia Doped Ceria (GDC)
,”
Third International Conference on Heterogeneous Material Mechanics, Advances in Heterogeneous Material Mechanics
, Shanghai, China, May 22–26, pp.
75
78
.
28.
Zhang
,
F. C.
,
Luo
,
H. H.
, and
Roberts
,
S. G.
,
2007
, “
Mechanical Properties and Microstructure of Al2O3/Mullite Composite
,”
J. Mater. Sci.
,
42
(
16
), pp.
6798
6802
.
29.
Nieh
,
T. G.
,
Wadsworth
,
J.
, and
Sherby
,
O. D.
,
2005
,
Superplasticity in Metals and Ceramics
,
Cambridge University Press
,
Cambridge, UK
.
30.
Sekino
,
T.
, and
Niihara
,
K.
,
1995
, “
Microstructural Characteristics and Mechanical Properties for Al2O3/Metal Nanocomposites
,”
Nano Structured Mater.
,
6
(
5–8
), pp.
663
666
.
31.
Nikolova
,
D.
,
Stoyanova
,
E.
,
Stoychev
,
D.
,
Stefanov
,
P.
, and
Marinowa
,
T.
,
2006
, “
Anodic Behavior of Stainless Steel Covered With an Electrochemically Deposited Ce2O3–CeO2 Film
,”
Surf. Coat. Technol.
,
201
(
3–4
), pp.
1559
1567
.
32.
Valov
,
I.
,
Guergova
,
D.
,
Stoychev
,
D.
, et al.
2011
, “
Kinetics Studies on the Electrochemical Deposition of Ce3+/Ce4+ Oxides
,”
Chapter No17 in the Book “Nanotechnological Bases for Advanced Sensors,” NATO Science for Peace and Security Series-B: Physics and Biophysics
,
J.
Reithmaier
, ed.,
Springer
,
The Netherlands
, pp.
167
172
.
33.
Stoychev
,
D.
,
Stefanov
,
P.
,
Nikolova
,
D.
,
Aleksandrova
,
A.
,
Atanasova
,
G.
, and
Marinova
,
T.
,
2004
, “
Preparation of Al2O3 Thin Films on Stainless Steel by Electrochemical Deposition
,”
Surf. Coat. Technol.
,
180–181
, pp.
441
445
.
34.
Wheeler
,
D. W.
,
Zekonyte
,
J.
, and
Wood
,
R. J. K.
,
2013
, “
Mechanical Properties of Cerium and a Cerium–5 Wt% Lanthanum Alloy by Nanoindentation and Ultrasonic Velocity Measurements
,”
Mater. Sci. Eng. A
,
578
, pp.
294
302
.
35.
Yordanov
,
M.
,
Chobanov
,
P.
,
Stoyanova
,
E.
,
Stoychev
,
D.
,
Cherneva
,
S.
, and
Iankov
,
R.
,
2010
,
Influence of the Conditions of Deposition on Mechanical Properties of Anodically Formed Al2O3 Layers on Al 1050
, Vol.
1
,
Machine-building and Mechanics, BulKToMM Publishing House
, Varna, Bulgaria, pp.
81
85
.
36.
Datcheva
,
M.
,
Cherneva
,
S.
,
Stoychev
,
D.
,
Iankov
,
R.
, and
Stoycheva
,
M.
,
2011
, “
Determination of anodized aluminum material Characteristics by Means of Nanoindentation Measurements
,”
Mater. Sci. Appl.
,
2
(
10
), pp.
1452
1464
.
37.
Burroughs
,
P.
,
Hamnett
,
A.
,
Orchard
,
A. F.
, and
Thornton
,
G.
,
1976
, “
Satellite Structure in X-Ray Photoelectron Spectra of Some Binary and Mixed Oxides of Lanthanum and Cerium
,”
J. Chem. Soc., Dalton Trans.
,
17
(
17
), pp.
1686
1698
.
38.
Cherneva
,
S.
,
Stoychev
,
D.
, and
Iankov
,
R.
,
2012
, “
Measuring of Mechanical Properties of Electrochemically Deposited ZrO2, Ce2O3-CeO2 and La2O3 Films by Nanoindentation
,”
Chemické Listy
,
106
(S3), pp.
s438
s441
.
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