Performance Analysis of a Self-Decarbonizing Combustor

Hydrogen is envisioned to be a key decarbonization solution for fossil fuel-dependent power generation and aviation industries. At present, a significant fraction of the generated electrical power is derived from natural gas. As such, the external energy needed for hydrogen generation, often sourced from fossil fuels, results in CO₂ emissions, compromising overall carbon neutrality. Instead, the processes of hydrogen generation can be energetically coupled with the combustion process, in situ, to eliminate external energy requirements. To that end, a novel self-decarbonizing combustor (SDC) has been conceptualized, integrating methane pyrolysis with the combustion process that can in principle decarbonize many contemporary power generation technologies. The underpinning methane pyrolysis process enables in situ pre-combustion capture of solid carbon, while simultaneously generating hydrogen. Consequently, CO₂ emissions resulting from the combustion of processed, hydrogen-enriched fuel are mitigated. This study provides a comprehensive analysis, delineating the operating principle and the effect of some of the important governing parameters on the performance of the self-decarbonizing combustor. These parameters, including fuel temperature, residence time, pressure, and catalysis, are studied in the context of potentially applying the proposed concept to natural gas-based decarbonized electrical power generation. Investigating fuel chemistry, combustion exhaust, and carbon structure and morphology under varying process parameters enhances our comprehension of the SDC. Additionally, its self-sufficient nature eliminates the need for separate hydrogen production, storage, and transportation infrastructure, highlighting its potential as a scalable and realizable technology.