Flamelet Modeling of Pollutant Formation in a Gas Turbine Combustion Chamber Using Detailed Chemistry for a Kerosene Model Fuel

Combustion and pollutant formation in a gas turbine combustion chamber is investigated numerically using the Eulerian particle flamelet model. The code solving the unsteady flamelet equations is coupled to an unstructured computational fluid dynamics (CFD) code providing solutions for the flow and mixture field from which the flamelet parameters can be extracted. Flamelets are initialized in the fuel-rich region close to the fuel injectors of the combustor. They are represented by marker particles that are convected through the flow field. Each flamelet takes a different pathway through the combustor, leading to different histories for the flamelet parameters. Equations for the probability of finding a flamelet at a certain position and time are additionally solved in the CFD code. To model the chemical properties of kerosene, a detailed reaction mechanism for a mixture of n-decane and 1,2,4-trimethylbenzene is used. It includes a detailed $NOx$ submechanism and the buildup of polycyclic aromatic hydrocarbons up to four aromatic rings. The kinetically based soot model describes the formation of soot particles by inception, further growth by coagulation, and condensation as well as surface growth and oxidation. Simulation results are compared to experimental data obtained on a high-pressure rig. The influence of the model on pollutant formation is shown, and the effect of the number of flamelets on the model is investigated.